Low Loss Window Materials for Chemical Lasers

Abstract

The increasing interest and importance of chemical lasers has led to a demand for further materials studies at DF and HF chemical laser frequencies. In order to meet this demand a small cw chemical laser has been built for calorimetric measurements of the absorption coefficient. A wide variety of low loss materials has been studied at DF (3.8 micrometers) and HF (2.7 micrometers) frequencies. In conjunction with the absorption measurements, chemical cleaning and polishing techniques have been developed and applied to some materials to determine their effectiveness in minimizing surface absorption. Calorimetric measurements of the optical absorption coefficient at chemical laser frequencies are reported on single and polycrystalline alkaline earth fluorides and alkali halides, single crystal magnesium oxide, sapphire, magnesium fluoride, strontium titanate, and other materials. Infrared spectrometer data on the absorption coefficient as a function of frequency for most of the materials studied are presented. As in past work, these data serve to indicate the value of the absorption coefficients expected in the HF-DF frequency regime. The infrared scans also reveal impurity structure in a few oxide materials in this same region.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1975
Accession Number
ADA006671

Entities

People

  • James A. Harrington

Organizations

  • University of Alabama in Huntsville

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption Coefficients
  • Chemical Cleaning
  • Chemical Lasers
  • Crystal Structure
  • Crystals
  • Deuterium Fluoride Lasers
  • Emittance
  • Hydrogen Fluoride Lasers
  • Infrared Spectrometers
  • Infrared Spectroscopy
  • Laser Applications
  • Magnesium
  • Magnesium Compounds
  • Measurement
  • Polycrystals
  • Single Crystals
  • Spectroscopy

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Molecular Photonics/Laser Physics

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers