The Effects of Molecular Weight on the Pressure-Dependent Mechanical Properties of Polypropylene.

Abstract

Tensile tests and compression tests of polypropylene (PP) samples with different molecular weights have been carried out at various high pressures. Three different molecular weights were studied up to pressures of 6 kbars. At a given pressure, the effect of increasing molecular weight was to decrease the modulus and the strength. Observations could be explained by a pressure-induced shift of the beta-transition to room temperature. The elongation to fracture and the mode of fracture were found to depend on the molecular weight. The influence of the pressure medium on the observed tensile behavior was also studied. The pressure medium was observed to influence the deformation behavior only for the case of the lower molecular weight samples.

Document Details

Document Type
Technical Report
Publication Date
Jan 31, 1975
Accession Number
ADA006916

Entities

People

  • B. A. Newman
  • K. D. Pae
  • T. P. Sham

Organizations

  • Rutgers University–New Brunswick

Tags

DTIC Thesaurus Topics

  • Compression
  • Elongation
  • High Pressure
  • Mechanical Properties
  • Molecular Weight
  • Observation
  • Physical Properties
  • Polypropylene
  • Transitions

Readers

  • Mathematics or Statistics
  • Polymer Science and Technology
  • Reinforced Composite Materials