(Halomethyl)Arsenic Compounds. I. Primary and Secondary (Halomethyl)Arsines.

Abstract

(Chloromethyl)arsine and bis(chloromethyl)-arsine were prepared by the reduction of (chloromethyl)arsonic and bis(chloromethyl)arsinic acids, respectively. (Bromomethyl) and (iodomethyl) analogs of the primary and secondary arsines could not be prepared because of a facile rearrangement from C-functional to As-functional halides. Reactions of ClCH2AsH2 demonstrated a strongly reduced affinity for proton-proton exchange with hydrogen halide (in comparison to CH3AsH2), a reduction anticipated by group-electronegativity considerations. Nmr, ir, and mass spectral data are included.

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1972
Accession Number
ADA008110

Entities

People

  • Arnold L. Rheingold
  • Jon M. Bellama

Tags

DTIC Thesaurus Topics

  • Arsenicals
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Cooperation
  • Hydrogen
  • Maryland

Fields of Study

  • Chemistry

Readers

  • Data Mining and Knowledge Discovery.
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Molecular and Cellular Biochemistry