The Orientation of the Magnetic Axes of Quinoxaline and 2,3-Dichloroquinoxaline Triplets in a Durene Host Crystal from PMDR Methods.

Abstract

The polarizations of the zero-field (zf) transitions of quinoxaline and 2,3-dichloroquinoxaline in durene have been measured at 1.6K by phosphorescence microwave double resonance methods. From the results, the orientation of the magnetic axes of the triplet state of these molecules relative to the host lattice has been determined. Quinoxaline is found to dissolve substitutionally in durene, as has been concluded from ESR, while the magnetic axes of 2,3-dichloroquinoxaline are found to be rotated by 12 + or - 4 degrees around the short molecular axis.

Document Details

Document Type
Technical Report
Publication Date
Mar 28, 1975
Accession Number
ADA008436

Entities

People

  • Mostafa El-Sayed
  • Paul E. Zinsli

Organizations

  • University of California, Los Angeles

Tags

DTIC Thesaurus Topics

  • Microwaves
  • Molecules
  • Orientation (Direction)
  • Phosphorescence
  • Polarization
  • Quinoxalines
  • Resonance
  • Transitions

Fields of Study

  • Chemistry

Readers

  • Molecular Photonics/Laser Physics
  • Nanofabrication and Microfabrication.
  • Polymer Science and Technology