Infrared Properties of Mixed Lead-Bismuth Oxides,

Abstract

Five bismuth compounds with the cubic sillenite structure (I23), Bi12SiO20, Bi12GeO20, Bi12TiO2, Bi12ZnO19 and Bi12PbO19 were synthesized. Infrared and Raman spectra of these compounds and of Bi2O3 with and without N:O were measured. It is shown that fundamental mode frequencies in these covalent oxides are surprisingly high and that hope for an oxide window material has become vanishingly small.

Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1974
Accession Number
ADA008494

Entities

People

  • Regis J. Betsch
  • William B. White

Organizations

  • Pennsylvania State University

Tags

DTIC Thesaurus Topics

  • Bismuth
  • Bismuth Compounds
  • Bismuth Oxides
  • Elements
  • Films
  • Frequency
  • Group 15 Elements
  • Materials
  • Metals
  • Oxides
  • Post-Transition Metals
  • Raman Spectra
  • Spectra

Readers

  • Quantum Chemistry
  • Spectroscopy.
  • Superconducting Magnet Technology