Rates and Mechanisms of Reactions of Fluorine Containing Rocket Propellants.

Abstract

The rate of OF2 pyrolysis was rechecked using a magnesium reactor. The order was again found to be less than one for OF2 diluted with He, consistent with the previous data from the monel reactor. A mechanism was proposed consistent with this and other recent pyrolysis data. Attempts at obtaining reproducible, meaningful kinetic data for the H2-N2F4 reaction were not successful. The remainder of the effort was concentrated on obtaining rate data for the H2-OF2 reaction in the magnesium reactor. The stoichiometry was determined. There was no significant change in rate on increasing the surface area by a factor of three. The mechanistic implications of the rate data were discussed, however no completely satisfactory mechanism was devised.

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1975
Accession Number
ADA008873

Entities

People

  • Thomas Houser

Organizations

  • Western Michigan University

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Elements
  • Energetic Materials
  • Fluorine
  • Magnesium
  • Materials
  • Propellants
  • Pyrolysis
  • Rocket Propellants
  • Stoichiometry

Readers

  • Combustion science or combustion engineering.
  • Theoretical Analysis.