Solute-Solvent Interactions and Preferential Solvation: An NMR Study. An NMR Study.

Abstract

The object of this research was to study the interactions between ion and solvent and between ion and ion in electrolyte solutions in pure and mixed solvents. The primary concern was the development of new methods to determine the composition of the primary solvation shell of ions in solution. The solvation shell may contain solvent molecules and other ions. The former comes under the category of preferential solvation, while the latter is under ion pairing. A new method was developed for the detection of contact ion association in solutions of perchlorates. This method is based on the NMR relaxation time of the chlorine nucleus in the perchlorate ion.

Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1975
Accession Number
ADA009480

Entities

People

  • Thomas R. Stengle

Organizations

  • University of Massachusetts Amherst

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chlorine
  • Chlorine Compounds
  • Detection
  • Electrolytes
  • Halogen Compounds
  • Halogens
  • Molecules
  • Perchlorates
  • Relaxation Time
  • Solvation

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Systems Analysis and Design