Low Loss Window Materials for Chemical and CO Lasers,

Abstract

The optical absorption has been measured in a variety of materials (such as fluorides and titanates, which are candidates for service as low loss windows on DF-HF chemical or CO lasers. Measurements of the absorption coefficient beta at DF (3.8 micrometers) and HF (2.7 micrometers) frequencies were accomplished using cw chemical laser calorimetry. Beta as a function of frequency was obtained for the alkaline earth fluorides by measuring the spectral emittance at 100C. A phenomenological model has been employed to calculate beta for these hosts as a function of frequency. Good agreement is obtained between theory and experiment. The calorimetric results indicate that the absorption in most materials studied is limited by extrinsic processes. At HF frequencies, hydroxyl ions in the bulk or on the surface are believed responsible for the high beta values. At both DF and HF frequencies surface absorption appears to be strong owing in part to absorption by organics which are often used in surface finishing.

Document Details

Document Type
Technical Report
Publication Date
May 15, 1975
Accession Number
ADA010462

Entities

People

  • Bernard Bendow
  • D. L. Stierwalt
  • James A. Harrington
  • K. V. Namjoshi
  • S. S. Mitra

Organizations

  • Air Force Cambridge Research Laboratories

Tags

DTIC Thesaurus Topics

  • Absorption
  • Absorption Coefficients
  • Carbon Monoxide Lasers
  • Chemical Lasers
  • Coefficients
  • Emittance
  • Fluorides
  • Frequency
  • Lasers
  • Materials
  • Measurement
  • Micrometers
  • Optical Absorption
  • Spectral Emittance
  • Surface Finishing

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Optical Physics and Photonics.
  • Spectroscopy.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers