Monopropellant Droplet Decomposition for Large Activation Energies.

Abstract

The quasi-steady decomposition of a monopropellant droplet in a quiescent atmosphere is analyzed for an Arrhenius reaction. An analytical relation is obtained for the pre-exponential rate constant, or the Damkohler number, as a function of the droplet vaporization rate. For low values of the ambient temperature, the curve giving the vaporization rate in terms of the Damkohler number is S shaped and, thus, exhibits ignition-extinction characteristics. The lower bend of the S curve correspond to a nearly frozen regime, under which ignition conditions occur due to the large temperature sensitivity of the reaction rate. The upper bend of the S Curve corresponds to a regime, where nearly complete decomposition of the reactant occurs when it reaches a thin reactive-diffusive zone, after crossing a transport zone. This zone becomes thin, and thus planar, for large Damkohler numbers, resulting in a droplet decomposition rate proportional its radius. For low ambient temperatures a segment of the curve between the two bends of the S curve corresponds to a regime of partial decomposition in a thin reaction zone.

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1974
Accession Number
ADA010930

Entities

People

  • Amable Liñán

Tags

DTIC Thesaurus Topics

  • Atmospheres
  • Burning Rate
  • Chemical Reaction Properties
  • Chemical Reactions
  • Crossings
  • Decomposition
  • Dissociation
  • Energy
  • Extinction
  • Heat Of Activation
  • Ignition
  • Lysis
  • Monopropellants
  • Sensitivity
  • Transition Temperature
  • Vaporization

Readers

  • Approximation Theory.
  • Combustion science or combustion engineering.
  • Materials Science (Mechanical Engineering).