Out-of-Plane Metalloporphyrin Complexes.
Abstract
Recent progress in the chemistry of synthetic metalloporphyrins has shown that the porphyrin moiety can act as a bi-, tri- or hexadentate ligand, as well as the usual tetradentate ligand. In addition, the metal ion has been observed to possess 4, 5, 6 or 8-coordination. While the last few years has seen a substantial growth in metalloporphyrin research, a rapid development in a unique area of chemistry, out-of-plane metalloporphyrins, has been particularly noticeable. It would be impossible to cover all the developments in the space available; thus, this article confines the discussion to the synthesis and structure of these out-of-plane complexes with unusual geometries.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jun 16, 1975
- Accession Number
- ADA012429
Entities
People
- Glenn A. Taylor
- Minoru Tsutsui
Organizations
- Texas A&M University