STRESS CORROSION CRACKING CONTROL MEASURES. 5. TITANIUM ALLOYS,

Abstract

The practical SCC hazards to titanium involve a wide range of environments. For some groups of environments, such as natural waters and nearly neutral aqueous solutions, the cracking occurs only in the presence of a pre-existing crack-like flaw, and fracture mechanics type tests readily characterize the SCC behavior of alloys. Unalloyed titanium and the widely used Ti-6%al-4%V alloy are reasonably resistant to SCC in these environments. For N2O4 and red fuming nitric acid, practical control of the problem is available through controlling the composition of the oxidizers, for which standard specifications are available. For the hot salt cracking problem during heat treatment, meticulous cleanliness of the titanium, backed up preferably by excluding moisture and oxygen from the heat treating atmosphere, serves to control the problem. Though untried in practice, a nickel barrier paint may be useful when contamination at elevated temperatures cannot be avoided in service; the alternative is to design for low operating stresses. For some environments, such as methanol, mercury, cadmium or silver, the strategy is to exclude them from titanium surfaces.

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1975
Accession Number
ADA013612

Entities

People

  • B. F. Brown

Organizations

  • American University

Tags

DTIC Thesaurus Topics

  • Alcohols
  • Alloys
  • Aqueous Solutions
  • Corrosion
  • Environment
  • Fracture (Mechanics)
  • Heat Treatment
  • Material Degradation Processes
  • Materials
  • Mechanics
  • Nitric Acid
  • Rocket Oxidizers
  • Stress Corrosion
  • Stress Corrosion Cracking
  • Titanium
  • Titanium Alloys

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Surface Engineering/Surface Coating Technology.
  • Systems Analysis and Design