Casting of Halide and Fluoride Alloys for Laser Windows

Abstract

The main objective of this program is to demonstrate the feasibility of fusion casting of alkali halides and alkaline earth fluorides for high power laser window applications. The main effort deals with the fabrication and property evaluation of the alkaline earth fluorides. During the second six months of this program high quality castings of both CaF2 and SrF2 were fabricated. Castings of CaF2 were attempted in an inert atmosphere of purified argon (1-50 torr). Calorimetrically measured 5.25 micrometer bulk absorption coefficients for cast CaF2 are being consistently attained near 0.00042/cm regardless of the starting material. In preliminary results the 5.25 micrometer bulk absorption coefficient of cast SrF2 lies near 0.000067/cm for an ingot using single crystal chips as starting material and lies near 0.00017/cm for an ingot cast from purified 'reagent' grade powder. The preliminary results also show that SrF2 is equivalent in strength to CaF2 and that polycrystalline cast material is equivalent in strength to single crystal material.

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Document Details

Document Type
Technical Report
Publication Date
Apr 15, 1975
Accession Number
ADA014864

Entities

People

  • J. Pappis
  • R. T. Newberg

Organizations

  • RTX

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption Coefficients
  • Air Force
  • Coefficients
  • Controlled Atmospheres
  • Crystal Structure
  • Crystals
  • Energy
  • Grain Size
  • Heat Treatment
  • High Vacuum
  • Materials
  • Measurement
  • Mechanical Properties
  • Optical Absorption
  • Optical Materials
  • Partial Pressure
  • Single Crystals

Fields of Study

  • Materials science

Readers

  • Metallurgy
  • Spectroscopy.
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers