Solid Propellant Kinetics. V. Fuel-Oxidizer Reaction Rates from Heterogeneous Opposed Flow Diffusion Flame

Abstract

A theoretical model is presented relating the gas dynamics and chemical kinetics of the opposed flow diffusion flame formed in the stagnation region between two opposing streams of gaseous reactants, one originating from the surface of a subliming solid, such as ammonium perchlorate. At low gas flows the regression rate of the solid is controlled by the physical properties of the system, including the net heat of gasification, the heat of combustion, and the transport parameters. At high gas flows a limiting solid regression rate is attained due to reaction-rate limitations that cause incomplete combustion of the reactants. The theoretical model developed for the heterogeneous opposed flow diffusion flame allows interpretation of the limit in solid regression rates in terms of global reaction kinetics.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1974
Accession Number
ADA015899

Entities

People

  • C. M. Ablow
  • H. Wise

Organizations

  • SRI International

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Ammonium Perchlorate
  • Boundary Layer
  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Combustion
  • Conductivity
  • Energy Conservation
  • Equations
  • Exothermic Reactions
  • Gaseous Fuels
  • Heat Of Activation
  • Molecular Weight
  • Phase
  • Solid Propellants
  • Specific Heat
  • Surface Temperature

Readers

  • Combustion and Flow Dynamics.
  • Molecular Photonics/Laser Physics
  • Rocket Propulsion.