Improved Manganese Phosphate Coatings

Abstract

Work was conducted to determine the mechanism by which superior manganese phosphate coatings are produced. The phosphate coatings were applied at temperatures above 212 F and with manganese-organic compounds added to the phosphating solution. Experimental baths and solubility studies have shown that the manganese concentration in the bath is critical and that the main function of the manganese-organic compounds is to increase the manganese concentration. The necessity of a processing temperature higher than 212 F has been attributed to an exponential increase in the reaction rate constant with temperature for the conversion of manganese dihydrogen phosphate (Mn(H2PO4)2) to manganese phosphate (Mn3(PO4)2).

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1975
Accession Number
ADA018131

Entities

People

  • Henry Crain

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Acids
  • Army
  • Army Training
  • Coatings
  • Conversion
  • Corrosion
  • Corrosion Resistance
  • Hydrogen Electrodes
  • Manganese
  • Materials
  • Metals
  • Organic Compounds
  • Phosphate Coatings
  • Salt Spray Tests
  • Sugar Acids
  • Test And Evaluation

Readers

  • Surface Engineering/Surface Coating Technology.