Fabrication and Investigation of Nickel-Alkaline Cells. Part 1. Fabrication of Nickel-Hydroxide Electrodes Using Electrochemical Impregnation Techniques

Abstract

Several electrochemical impregnation techniques for deposition of active Nickel-Hydroxide inside nickel sinters have been investigated. The most favorable means of impregnation appears to be deposition from alcoholic nitrate solutions. Formation cycling of electrodes made from the various techniques has been performed using 20-50% overcharge for 10-30 cycles. Some electrodes show capacities as high as 9.5 ampere-hours per cubic inch after these cycles. The alcohol process has been scaled to pilot production, and several 20-25 A-H vented Nickel-Cadmium cells were constructed using cadmium electrodes fabricated from another electrochemical technique. These cells show vastly improved charge acceptance, at a wide temperature range, over state-of-the-art vented aircraft cells and improved cycle life at high temperatures and deep depths of discharge.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1975
Accession Number
ADA018517

Entities

People

  • David F. Pickett

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Alcohols
  • Aqueous Solutions
  • Assembly
  • Cells
  • Chemical Synthesis
  • Chemistry
  • Construction
  • Current Density
  • Deep Depth
  • Fabrication
  • High Temperature
  • Manufacturing
  • Materials
  • Photoelectrochemical Cells
  • Pilot Plants
  • Production

Fields of Study

  • Materials science

Readers

  • Analytical Chemistry
  • Battery Technology and Engineering