External Catalyst Breakup Phenomena

Abstract

The overall objective of the work in this program is to investigate the external breakup mechanisms of Shell 405 catalyst so as to establish an understanding of the phenomenon which can aid in extending catalyst life in use in monopropellant hydrazine thrusters. The program involves the joint efforts of Exxon Research and Engineering Company, McDonnell Douglas Astronautics Company and TRW Inc. The program involves both experimental and analytical studies of potential catalyst breakup mechanisms. A number of different mechanisms were identified for study following a review of the literature and other available information. To date fourteen specific mechanisms from the general areas of fluid dynamic erosion, pressure crushing, differential thermal expansion, particle movement, thermal shock and pore pressure gradients have been screened. Major breakup mechanisms or factors identified to date include particle to particle crushing as a result of various static pressure crushing forces, build- up of pressure within the catalyst pore as a result of imbibed liquid hydrazine the fact that a voided thruster bed has sufficient gas velocity for particle movement, and loss of catalyst physical properties such as crush strength with use. Other significant mechanisms or factors identified include fluid dynamic erosion from a pulsed liquid stream and from particulates in hydrazine and thermal shock during liquid quench cooldown. Five mechanisms or factors were judged not to be significant. Although the program is not completed, the results to date were examined for thruster design implications.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1975
Accession Number
ADA019213

Entities

People

  • W. F. Taylor
  • W. T. Webber

Tags

Communities of Interest

  • Ground and Sea Platforms
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Engineering
  • Chemical Reactions
  • Chemistry
  • Crystal Structure
  • Failure Mode And Effect Analysis
  • Geometry
  • Heat Energy
  • Heat Transfer
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Mechanical Working
  • Mechanics
  • Pressure Distribution
  • Rocket Engines
  • Test And Evaluation
  • Thermodynamics

Readers

  • Aerosol Science/Aerosol Physics
  • Rocket Propulsion.
  • Theoretical Analysis.

Technology Areas

  • Space
  • Space - Hall-Effect Thruster