Exploratory Aluminum-Chlorine Thermally Activated Battery: Single Cell Experiments.

Abstract

Single cells which can be considered prototypes of the individual cells in a low temperature pile type thermal battery have been constructed and characterized. Both binary AlCl3,NaCl and ternary AlCl3. NaCl, KCl electrolytes were studied. Eight concentration cells with aluminum electrodes were tested. Twenty-three formation cells with aluminum anodes were studied; cathode configurations tested in formation cells included: (1) Cl2, graphite, W; (2) NiCl2, graphite, Ni and (3) C4.5F, graphite, W. Materials employed to immobilize the electrolyte included fiberglass felt and Cab-O-Sil. Operating temperatures ranged from 109 C to 222 C. Key findings: (1) NaAlCl4 melts can be effectively immobilized by Cab-O-Sil; (2) Current densities in excess of 1 mA/sq cm can be achieved with formation cells; (3) Both NiCl2, graphite, Ni and C4.5F, graphite, W are attractive candidate cathodes for formation cells. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1976
Accession Number
ADA021664

Entities

People

  • David W. Seegmiller
  • G. Dana Brabson
  • John K. Erbacher
  • Lowell A. King

Organizations

  • United States Air Force Academy

Tags

DTIC Thesaurus Topics

  • Aluminum
  • Chlorine
  • Current Density
  • Electrodes
  • Electrolytes
  • Fiberglass
  • Fibers
  • Graphitic Materials
  • Low Temperature
  • Materials
  • Prototypes
  • Thermal Batteries

Fields of Study

  • Materials science

Readers

  • Battery Technology and Engineering
  • Mathematics or Statistics
  • Surface Engineering/Surface Coating Technology.