2,4,6-Tripicryl-s-Triazine, TPT; It's Crystallization and Crystal Density Determinations

Abstract

2,4,6-Tripicryl-s-triazine, TPT, is normally crystallized from acetone-methanol solutions as an acetone solvate. The solvent of crystallization may be removed by heating, leaving a noncrystalline or pseudo crystalline solid, the density of which is not the true crystal density. Previous efforts to prepare crystalline TPT have not been successful. In this work, TPT was crystallized from a variety of solvents. In most cases, solvates were formed; however, crystallization from m-dichlorobenzene produced crystals that were non-solvates, and were large enough for crystal density determinations. The density of these crystals was found to be 1.724 g/cc.

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Document Details

Document Type
Technical Report
Publication Date
Mar 08, 1976
Accession Number
ADA023464

Entities

People

  • Joseph C. Dacons

Organizations

  • Naval Ordnance Laboratory

Tags

Communities of Interest

  • Counter IED
  • Weapons Technologies

DTIC Thesaurus Topics

  • Acetic Acid
  • Alcohols
  • Anhydrides
  • Aqueous Solutions
  • Charge Transfer
  • Chromatographic Analysis
  • Crystallization
  • Crystals
  • Drying
  • Drying Apparatus
  • Explosives
  • Heat Energy
  • Laboratory Equipment
  • Melting
  • Melting Point
  • Methanols
  • Triazines

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Solar Photovoltaics and Thermoelectric Devices.
  • Thin Film Deposition Science.