Deactivation of HCl (v = 1) and DCl(v = 1) by H and D Atoms at T = 295 K

Abstract

The techniques of isothermal calorimetry (for H atoms) and laser- induced fluorescence (for HCl(1)) were combined to yield absolute rate coefficients for H and D atom removal of HCl(1) and DCl(1). At T = 295 K, the rate coefficients for H + HCl(1), D + HCl(1), H + DCl(1), and D + DCl(1) are (4. 6 + or - 1.4) X 10 to the 12th power, (6.5 + or - 2.0) X 10 to the 12th power, (1.15 + or - 0.3) X 10 to the 12th power, and (1.2 + or - 0.4) X 10 to the 12th power cc/mol-sec, respectively.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1976
Accession Number
ADA025252

Entities

People

  • Jerry F. Bott
  • Richard F. Heidner Iii

Organizations

  • The Aerospace Corporation

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Communities of Interest

  • Advanced Electronics
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Amplifiers
  • Arrhenius Equation
  • Chemical Kinetics
  • Chemical Reactions
  • Chemistry
  • Coefficients
  • Corporations
  • Detection
  • Experimental Data
  • Fluorescence
  • Laser Induced Fluorescence
  • Lasers
  • Materials
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  • Physics Laboratories
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  • Analytical Mechanics
  • Molecular Photonics/Laser Physics

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers