Structure-Property Correlations in Primary Explosives.

Abstract

In the first step, the authors measured the time for deflagration to detonation (DDT) as a function of chemical structure for cast primary explosives. The compound methyl-nitrotetro zole was synthesized and confirmed the presence of the nitro group in the compound by infrared analysis. By additivity methods, the heats of formation and the crystal density were estimated. The apparatus for measuring time to DDT in primary explosives was assembled and tested with pressed pellets of lead azide. The second step in this project is to develop and test a model for predicting the time to DDT for cast primary explosives. It was anticipated that the model would be based on Macek's work for secondaries. The third step is to reintroduce some of the physical variables such as density.

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1975
Accession Number
ADA027090

Entities

People

  • Craig M. Tarver
  • John M. Guimont
  • Marion E. Hill
  • Robert Shaw

Organizations

  • SRI International

Tags

Communities of Interest

  • Counter IED

DTIC Thesaurus Topics

  • Azides
  • Deflagration
  • Detonations
  • Energetic Materials
  • Explosions
  • Explosives
  • High Explosives
  • Lead Azides
  • Materials

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Rocket Propulsion.