The Kinetics of Silica Dissolution from Volcanic Glass in the Marine Environment.

Abstract

The rate of silica dissolution from volcanic glass in seawater and NaCl solutions can be described by a combination of simultaneous first order reactions. Models that contain parabolic-rate diffusion processes did not agree with these data. Laboratory experiments studied the silica dissolution rate from one rhyolitic and two basaltic glasses in the pH range of 7.3 to 8.3 and at temperatures of 25, 60, and 90 C. The early flux of silica from these samples was greatest for the basaltic reticulite pumice, less for the basaltic hyaloclastite glass, and least for the rhyolitic obsidian. Seawater collected adjacent to a basaltic lava flow as it entered the ocean was enriched in silica, iron, and manganese; but cobalt, copper, nickel, lead, chromium, and zinc concentrations were not significantly different from the control samples.

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1975
Accession Number
ADA027593

Entities

People

  • Glenn Charles Sicks

Tags

DTIC Thesaurus Topics

  • Amorphous Materials
  • Buildings And Structures
  • Chromium
  • Diffusion
  • Elements
  • Environment
  • Glass
  • Kinetics
  • Manganese
  • Materials
  • Metals
  • Obsidian
  • Physics Laboratories
  • Research Facilities
  • Transition Metals

Fields of Study

  • Geology

Readers

  • Geotechnical Engineering.
  • Materials Science and Engineering.
  • Surface Engineering/Surface Coating Technology.