Photoluminescence of Gallium Phosphide.

Abstract

The photoluminescence emission spectra from four GaP crystals were studied in order to characterize their impurity content. The temperature dependent behavior of the emission spectra was studied in the temperature range of 4.2 degrees Kelvin to 100 degrees Kelvin using liquid helium and the cold gas from evaporating liquid helium as the coolant. An argon-ion laser operating at 4579A and 150mw power output was used to excite the crystals, and the spectra were detected photoelectrically. The inadvertent impurities present in the crystals are nitrogen, sulfur, carbon, and silicon, with nitrogen related spectra seen in only one sample. Copper doping in one sample seemed to eliminate any evidence of silicon contamination, but switching from quartz to graphite growth crucibles did not. Two distinct spectral features were seen that were not readily identifiable from the literature, and these were attributed to the presence of silicon. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1976
Accession Number
ADA029011

Entities

People

  • Harley H. Pritchard Jr

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Argon Lasers
  • Cold Gases
  • Contamination
  • Crucibles
  • Emission
  • Emission Spectra
  • Fluids
  • Gases
  • Graphitic Materials
  • Impurities
  • Ion Lasers
  • Lasers
  • Liquids
  • Nitrogen
  • Photoluminescence
  • Spectra

Readers

  • Materials Science and Engineering.
  • Spectroscopy.
  • Thermal Physics or Thermal Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics
  • Microelectronics - Graphene