Determination of Long Term Compatibility of Hydrazine with Selected Materials of Construction. Design Criteria and Guidance

Abstract

An electrochemical accelerated compatibility test method is described. This description includes the theory of the test method, the equipment required to perform the tests and the method for the preparation of the test specimens. A complete step by step experimental procedure is outlined which includes the range of values used for experimental variables such as scan rate, voltage scale, electrolysis current and relaxation time. The determination of metal dissolution and its relationship to hydrazine decomposition rates is discussed. The results of a series of tests incorporating variables such as metal, metal pretreatment, hydrazine impurities, temperature and time are presented. A statistical analysis of the results using a Graeco-Latin cube design is included which evaluates the relative effect of each of the variables on the value of the equilibrium decomposition current (isubo). Recommendations for material selection and cleaning and passivation techniques are presented in the light of the of the experimental results.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1976
Accession Number
ADA030320

Entities

People

  • C. T. Brown

Organizations

  • United Technologies Corporation

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Aluminum Alloys
  • Arrhenius Equation
  • Chemical Reaction Properties
  • Chemical Reactions
  • Decomposition
  • Electrodes
  • Electrolysis
  • Electrolytes
  • Electron Transfer
  • Equations
  • Information Science
  • Materials
  • Propellants
  • Relaxation Time
  • Statistical Analysis
  • Test Methods
  • Titanium Alloys

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  • Computational Modeling and Simulation
  • Electrochemical Engineering/ Fuel Cell Technologies
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