Elastic Interaction of Two Atoms Adsorbed on a Solid Surface

Abstract

The long-range interaction of two adsorbed atoms mediated by the elastic distortion of the substrate is calculated classically for an elastically isotropic substrate. For identical atoms, the interaction is repulsive; for different atoms, it can be repulsive or attractive. It varies as 1/rho cubed with the distance rho between the two adsorbed atoms. This is the same spatial dependence as for the dipole-dipole interaction between two adsorbed atoms. For two xenon atoms adsorbed on silver, the elastic interaction is about one order of magnitude smaller than the dipole-dipole interaction. The interaction energy is inversely proportional to the shear modulus of the substrate, so that it may become quite large near a distortive phase transition.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1976
Accession Number
ADA030910

Entities

People

  • Kin-Hing Lau
  • Walter W. Kohn

Organizations

  • University of California, San Diego

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Atoms
  • California
  • Crystal Lattices
  • Crystal Structure
  • Crystals
  • Cubic Lattices
  • Dipole Moments
  • Displacement
  • Distortion
  • Equations
  • Fourier Series
  • Ground State
  • Perturbation Theory
  • Phase Transformations
  • Shear Modulus
  • Substrates
  • Two Dimensional

Fields of Study

  • Physics

Readers

  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.
  • Structural Dynamics.