Organic Derivatives of Heteropoly Molybdates.

Abstract

Heteropoly molybdate(VI) and tungstate(VI) anions are typically ionic oxometallate clusters of high symmetry, large size, and high ionic weight. They are usually the anions of strong acids, they form salts that are soluble in a variety of aqueous and nonaqueous solvents, and they may also undergo a series of reversible electron transfer reactions to yield mixed valence (V, VI) heteropoly blues. It has been customary to represent the structures of heteropoly anions as assemblages of metal-oxygen polyhedra which share corners, edges and occasionally faces, and to invoke electrostatic arguments (Pauling's Rules) to rationalize bond-lengths and angles. (Author)

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1976
Accession Number
ADA032543

Entities

People

  • Carl O. Quicksall
  • Judith K. Stalick
  • L. M. Rajdovic
  • Michael T. Pope
  • Wonsuk Kwak

Organizations

  • Georgetown University

Tags

DTIC Thesaurus Topics

  • Chemistry
  • Electron Transfer
  • Governments
  • Military Research
  • Molybdates
  • Molybdenum
  • Plastic Explosives
  • United States
  • United States Government
  • Universities

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Quantum Chemistry

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene