Theory of Shallow Donor States with a Strong Central Cell Perturbation

Abstract

A new theory for shallow donor states with a strong central cell perturbation is presented. The impurity wave function is expanded in terms of generalized Wannier functions, equivalent to the eigenfunctions of the periodic lattice with the strong central cell perturbing potential. The single unknown parameter of this theory can be fitted by comparison with the observed binding energy. The theory is applied to the impurity states of As, P and Sb in Silicon. The Fermi contact constants for the Si29 lattice nuclei surrounding the impurity are calculated and compared to the ENDOR experiments of Hale and Mieher and to recent calculations, using a different method, by Ivey and Mieher. Some elucidations of the theory of Ivey and Mieher are offered. In contrast to the conclusions of these authors, it is found that a suitable form of the Effective Mass Theory can account for the observations within an accuracy of about 10-15%.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1976
Accession Number
ADA032570

Entities

People

  • Joan R. Onffroy

Organizations

  • University of California, San Diego

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • California
  • Coefficients
  • Color Centers
  • Conduction Bands
  • Crystal Lattices
  • Crystal Structure
  • Dielectric Permittivity
  • Energy Bands
  • Energy Levels
  • Impurities
  • Magnetic Fields
  • Military Research
  • Molecular Orbital Theory
  • Perturbations
  • United States
  • Valence Bands
  • Wave Functions

Fields of Study

  • Physics

Readers

  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.
  • Thin Film Deposition Science.