High Energy Chemical Reactivity.

Abstract

Gas-liquid critical constants have been measured for fluorinated ethanes and used to test empirical corresponding states relations for the determination of molecular force constants. These empirical relations appear to be applicable to essentially all substances for which critical data are available. A radio-tracer technique has been developed for the investigation of unimolecular collisional energy transfer for 14CH3CF3 activated by 14CH3 plus CF3 recombination. This method has yielded a significant improvement in sensitivity with respect to existing techniques. It appears to be widely applicable for high accuracy studies of unimolecular reactions.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1976
Accession Number
ADA033995

Entities

People

  • John W. Root

Organizations

  • University of California, Davis

Tags

DTIC Thesaurus Topics

  • Accuracy
  • Chemical Reactions
  • Energy
  • Energy Transfer
  • High Energy

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Molecular Photonics/Laser Physics
  • Theoretical Analysis.