Attempted Preparation of Polyorganonitriles.

Abstract

A variety of triazine monomers have been screened for polymerizability using metallic and nonmetallic catalysts at elevated temperatures. Cyanuric chloride, bromo-chloro-triazines, 2,4-dichloro-6-phenyl-triazine, are either inert or react slowly with or without chemical side reactions to give low molecular weight products. The novel monomers mono- and bis-(trifluoroethoxy)-chloro-triazines react degradatively to give low molecular weight products with extensive loss of volatile materials which are thought to be fluorine containing materials. Preparation of the potential monomer trifluoroethyl cyanate has led to simultaneous formation of nonvolatile product which may contain polymeric material. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1976
Accession Number
ADA034143

Entities

People

  • Arthur H. Gerber

Tags

Communities of Interest

  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkanes
  • Boiling Point
  • Chemical Properties
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Chromatographic Analysis
  • Cyanides
  • Elastomers
  • Materials
  • Mechanical Properties
  • Military Research
  • New York
  • Nitrogen
  • Nitrogen Compounds
  • Organic Chemistry
  • Side Reactions

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Engineering.
  • Polymer Science and Technology