A Mass Spectrometer Investigation of the Chemistry of Plateau Burning Propellants.

Abstract

A mass spectrometer study has been conducted involving double base plateau burning propellants containing lead and copper organic salts. The pyrolysis and combustion of the metallic salts were also investigated. The results revealed that the metallic salts decompose to the gaseous and condensed phase metallic elements. The gaseous lead or copper atoms then react with the nitrate esters to form compounds such as PbNO2 and CuNO2, which are stable in the intermediate temperature zones. When the nitrites enter the combustion zone they react to produce the metallic hydroxides and oxides as predicted by the thermodynamic equilibria. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1976
Accession Number
ADA035602

Entities

People

  • Milton Farber
  • R. D. Srivastava

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Burning Rate
  • Capillary Electrophoresis
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Combustion Products
  • Decomposition
  • Insensitive Explosives
  • Lead Compounds
  • Lead Oxides
  • Mass Spectrometers
  • Metal Oxides
  • Neon
  • Oxides
  • Propellants

Fields of Study

  • Chemistry

Readers

  • Combustion and Flow Dynamics.
  • Organic Chemistry