Unusual Metalloporphyrins. Synthesis and Properties of a Dimetallic Boron Porphyrin Complex.

Abstract

Reaction of BC13 acetonitrile adduct with tetraphenylporphine affords the corresponding chloro-boron complex. Chromatography of this chelate on alumina results in ligand exchange producing an unusual tetrahydroxydiboron porphyrin. This complex is characterized by visible, ir, nmr, and mass spectrometry, as well as elemental analysis. The diboron derivatives are easily demetallated in solution and are formulated as having out of place structures. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1977
Accession Number
ADA035836

Entities

People

  • Carl J. Carrano
  • Minoru Tsutsui

Organizations

  • Texas A&M University

Tags

Communities of Interest

  • Air Platforms
  • Biomedical

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Acetonitrile
  • Chemical Synthesis
  • Chemistry
  • Distortion
  • Infrared Spectra
  • Mass Spectra
  • Mass Spectrometers
  • Mass Spectrometry
  • Measurement
  • Spectra
  • Spectrometers
  • Spectrometry
  • Spectroscopy
  • Universities
  • Visible Spectra

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry