Reactions between AlO Sub x and O Atoms.
Abstract
Rate coefficients for the reactions AlO + O yields Al + O2, AlO2 + O yields AlO + O2, Al + SO2 yields AlO + SO and Al + NO + M yields AlNO + M from high-temperature fast flow reactor (HTFFR) measurements are reported. D(Al-O) was determined to be > or = 126 kcal/mole. Emission of chemiluminescence continua (280 nm to > 725 nm) in mixtures of atomic Al with (i) O atoms and (ii) N atoms occurs, via not yet elucidated addition mechanisms, with a rate coefficient of 10 to the -12th power to 10 to the -11th power ml/molecule/sec. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1977
- Accession Number
- ADA036360
Entities
People
- Arthur Fontijn