Unimolecular Decay Photoexcited Tetramethyldioxetane Probed by Picosecond Spectroscopy.

Abstract

The photolysis of tetramethyldioxetane at 264 nm was probed using picosecond spectroscopic techniques. Singlet exited acetone was one of the observed products. The rise time for acetone fluorescence was determined to be less than 10 psec. A mechanism consistent with these results is proposed. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Feb 25, 1977
Accession Number
ADA036680

Entities

People

  • Gary Schuster
  • Ja-young Koo
  • Kenneth J. Kaufmann
  • Kevin K. Smith

Organizations

  • University of Illinois Urbana–Champaign

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes
  • Weapons Technologies

DTIC Thesaurus Topics

  • California
  • Cameras
  • Chemical Reactions
  • Chemistry
  • Civil Engineering
  • Decomposition
  • Dissociation
  • Emission
  • Emission Spectra
  • Excitation
  • Fluorescence
  • Military Research
  • Photochemical Reactions
  • Photolysis
  • Quantum Yields
  • Spectroscopy
  • Streak Cameras

Fields of Study

  • Chemistry

Readers

  • Clinical Trial Research.
  • Optical Physics and Photonics.
  • Organic Chemistry