Unusual Metalloporphyrins, Phosphorus Complexes of Tetraphenylporphine.
Abstract
The synthesis and spectral properties of several phosphorus complexes of tetraphenylporphine (TTP) are reported. The compounds appear to have the form (TPP)P(V)X(2+)Y(-) as previously reported by Gouterman et al. for the analogous octaethylporphyrin (OEP) complexes. The electronic and nmr spectra show a striking dependence on the nature of the anionic ligand X, which has not previously been reported and appears to be inconsistent with a symmetrical in-plane structure. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1977
- Accession Number
- ADA036681
Entities
People
- Carl J. Carrano
- Minoru Tsutsui
Organizations
- Texas A&M University