Electrically Initiated HCl Chemical Laser and Threshold Excitation of XeF and KrF Lasers

Abstract

The report describes the results of two separate experimental investigations. The first concerns the electrical excitation of the HCl chemical laser and was motivated by the potential improvement of the laser performance by the vibrational enhancement of the reaction Cl + H2(v=1) yields HCl(v=v,1) + H. Detailed kinetic modelling of the e-beam and e-beam sustained discharge experiments was used in the interpretation of the experimental data. The rate constant for the vibrationally enhanced reaction was 40 times larger than for the reaction with H2(v=0) at T = 300K. This enhanced rate is not fast enough to lead to efficient use of the H2(v=1) excited by electron impact. The maximum electrical to laser conversion efficiency obtained was 3 percent. The second part of the report describes measurements of the threshold pumping power density in e-beam sustained discharge excitation of KrF and XeF lasers. Stable discharges were obtained in Ar-Kr-F2 and Ar-Xe-NF3 mixtures at 1 atm for times greater than 0.5 microsecond and lasing pulse width as long as 0.5 microsecond. The threshold pump power densities varied inversely with the cavity build up time. Based on the present results it is evident that efficient laser operation in KrF and XeF could be achieved in a 1-m long sustained discharge with input power densities in the range of 50 to 100 kW/cu cm over a 1 microsecond time scale.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1977
Accession Number
ADA037732

Entities

People

  • A. L. Pindroh
  • C. H. Fisher
  • L. Y. Nelson
  • R. E. Center
  • S. R. Byron

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Boltzmann Equation
  • Charged Particles
  • Chemical Kinetics
  • Chemical Reactions
  • Current Density
  • Electric Discharges
  • Electron Beams
  • Electron Density
  • Electron Energy
  • Electrons
  • Energy
  • Energy Transfer
  • Measurement
  • Microsecond Time
  • Optical Materials
  • Plastic Explosives
  • Scattering

Fields of Study

  • Engineering
  • Physics

Readers

  • Plasma Physics.
  • Pulsed Power and Plasma Physics.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics