Hexakis(Aniline)Phthalocyaninatoiron(II), Hexakis(Aniline-d7) Phthalocyaninatoiron(II), and Other Related Highly Selective NMR Shift Reagents.
Abstract
The significant properties of three good iron (II) phthalocyanine nmr shift reagents, FePc, FePc(NH2C4H9)2, and FePc(ND2C4D9)2 and two superior shift reagents of the same type, FePc(NH2C6H5)6 and FePc(ND2C6D5)6 are described and discussed. Some of the kinds of compounds the latter two generally can be expected to function with and some of the kinds of compounds they generally can be expected not to function with are given, i.e., imidazoles, pyridines, pyrrolidenes, and primary aliphatic amines; and pyrroles, secondary aliphatic amines, tertiary aliphatic amines, aromatic amines, alcohols, ethers, and many other compounds carrying oxygen functions, respectively. Where they can be clearly identified, properties of these compounds which are important to the behavior they show toward the reagents are alluded to. Throughout the value of the selectivity which the reagents show both monofunctional and polyfunctional compounds is emphasized. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jun 14, 1977
- Accession Number
- ADA041036
Entities
People
- Clement K. Choy
- J. Robert Mooney
- Malcolm E. Kenney
Organizations
- Case Western Reserve University