A Shock Tube Study of the H2/O2/CO/Ar and H2/N2O/CO/Ar Systems.
Abstract
Emissions at 450 nm and 4.27 micrometers have been measured when a variety of mixtures containing H2, CO, either O2 or N2O, and Ar were heated behind reflected shock waves to temperatures of 2000-2850 K and total concentrations near 5 x 10 to the 18th power molecule/cc. These emissions were used to obtain absolute concentration - time data for both oxygen atoms and carbon dioxide. The data were then compared to the results of numerical integrations of the likely mechanisms. It was observed that quantitative agreement between calculations and observations were obtained for the H2/CO/O2/Ar system using recent high temperature literature rate constants. For the H2/CO/N2O/Ar system, the rate constant for the reaction: H + N2O yields N2 + OH was adjusted so as to fit the data. Here it was found that a good fit to both (O) and (CO2) profiles could be achieved with k = 3 x 10 to the -9th power exp(-113kJ/RT) cc/molecule. Comparison to data at lower temperatures suggests that this might be another example of a 'Non-Arrhenius' rate constant. The implications of these results to studies of hydrocarbon oxidation are discussed. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- May 01, 1977
- Accession Number
- ADA041340
Entities
People
- Anthony M. Dean
- Don C. Steiner
- Edward E. Wang
Organizations
- Purdue University