Spectroscopic and Thermodynamic Investigations of Group V Halides

Abstract

The preparation and spectroscopic characterization of some mixed halogen and mixed halogen-cyanide compounds of phosphorous (V) are reported. Two solid-state forms of PCL5 have been investigated by differential scanning calorimetry. Solution reaction calorimetry have been used to measure the standard enthalpies of formation of the following crystalline compounds: P2Cl9Br, PCl3Br(+)BC4(-), PBr4(+)IBr2(-), PCl4(-), ICl4(-), PCl4(+)ICl2(-) and NI3NH3.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1977
Accession Number
ADA041491

Entities

People

  • Arthur Finch

Organizations

  • Royal Holloway, University of London

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Calorimetry
  • Chemistry
  • Crystal Lattices
  • Enthalpy
  • Government Procurement
  • Halogens
  • Heat Energy
  • Infrared Spectra
  • Materials
  • Materials Laboratories
  • Raman Spectra
  • Scanning
  • Spectra
  • Standards
  • Thermodynamic Properties
  • Vibrational Spectra

Fields of Study

  • Chemistry

Readers

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