Synthesis of Electrically-Conducting Organic Polymers: Halogen Derivatives of Polyacetylene, (CH)(X).

Abstract

When silvery films of the semiconducting polymer, trans ;'polyacetylene', (CH)x, are exposed to chlorine, bromine or iodine vapor, uptake of halogen occurs, and the electrical conductivity increases markedly (over seven orders of magnitude in the case of iodine) to give, depending on the extent of halogenation, silvery or silvery-black films, some of which have a remarkable high conductivity at room temperature. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jul 14, 1977
Accession Number
ADA041866

Entities

People

  • Alan G. Macdiarmid
  • Alan J. Heeger
  • Chwan K. Chiang
  • Edwin J. Louis
  • Hideki Shirakawa

Organizations

  • University of Pennsylvania

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • California
  • Charge Transfer
  • Chemistry
  • Conductive Polymers
  • Conductivity
  • Crystal Structure
  • Electrical Conductivity
  • Electrical Properties
  • Films
  • Halogenation
  • Halogens
  • Heat Of Activation
  • Materials
  • Military Research
  • New York
  • Polymers
  • United States

Readers

  • Materials Science and Engineering.
  • Organic Chemistry