Heats of Formation of Gaseous Metallic Halides.
Abstract
The heats of formation and dissociation energies for the silicon subchlorides and silicon subfluorides SiCl3(G), SiCl2(g), SiCl(g), SiF3(g), SiF2(g) and SiF were determined from high temperature thermochemical reactions of SiCl4(g) and SiF4(g) Ion intensities for the spacies involved in the reactions were obtained mass spectrometrically, leading to equilibrium constants and reaction enthalpies. The heats of formation were obtained by both second and third law methods and found to be in good agreement.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jun 01, 1977
- Accession Number
- ADA042035
Entities
People
- Milton Farber