Photolysis of RDX in Aqueous Solution. Initial Studies

Abstract

An experimental flow apparatus for the photolysis of RDX in aqueous solution is described. With this apparatus 98% of the RDX is destroyed at flow rates of 2500 ml/min. The end products formed include nitrogen gas, nitrous oxide gas, nitrate, and nitrite ions, formaldehyde and ammonia. One intermediate product has been identified as 1-nitroso-3-5-dinitro-1-3-5-triazacyclohexane. The primary photochemical steps involved in the photolysis are postulated. Areas for future work are outlined.

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Document Details

Document Type
Technical Report
Publication Date
Feb 22, 1977
Accession Number
ADA042199

Entities

People

  • Donald A. Kubose
  • John C. Hoffsommer

Organizations

  • Naval Ordnance Laboratory

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force Facilities
  • Aqueous Solutions
  • Benzene
  • Detectors
  • Dissolved Gases
  • Explosives
  • Flow Rate
  • Jet Propulsion
  • Laminar Flow
  • Lamps
  • Mass Spectra
  • Materials
  • Mercury Lamps
  • Nitrogen Compounds
  • Nitroso Compounds
  • Photolysis
  • Waste Water

Fields of Study

  • Chemistry

Readers

  • Agricultural Chemistry/Soil Science
  • Electrochemical Engineering/ Fuel Cell Technologies