Photochemical Studies of Secondary Nitramines. Part 2. Ultraviolet Photolysis and Ozonolysis of RDX in Aqueous Solutions

Abstract

The purpose of this study was to determine the feasibility of chemical degradation of RDX by ultraviolet-ozone process which had been previously developed for eliminating TNT from pink water. A study of UV photolysis at 254, 300 and 350 nm wavelengths, ozonolysis alone and a combination of O3 and UV (350 nm) on aqueous solutions of RDX was undertaken. The results indicate that O3 + UV in combination efficiently degrade RDX to gaseous products. These products are further compared with those obtained by photolysis and thermal decomposition of samples of crystalline RDX.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1977
Accession Number
ADA042715

Entities

People

  • Andrew F. Smetana
  • Suryanarayana Bulusu

Organizations

  • United States Army Armament Research, Development and Engineering Center

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Aqueous Solutions
  • Chemical Synthesis
  • Chemistry
  • Decomposition
  • Engineering
  • Engineers
  • Environmental Protection
  • Mass Spectra
  • Mass Spectrometry
  • Molecular Weight
  • Organic Chemistry
  • Organic Materials
  • Oxygen
  • Photolysis
  • Spectra
  • Spectroscopy

Fields of Study

  • Agricultural and Food sciences

Readers

  • Agricultural Chemistry/Soil Science
  • Chemistry (specifically Chemical Fluorescence)
  • Combustion science or combustion engineering.