Development of a Simple, Rapid Field Technique for Estimating Oil Concentrations in the Sediments.

Abstract

In the advent of an oil spill in coastal waters, it would be highly desirable to be able to detect the migration of oil into the sediments using techniques in the field rather than waiting for the results of sophisticated laboratory analysis. A rapid method for estimating the relative concentration of oil in sediments was developed and may effectively be employed in the field by non-technical personnel. The method employs a TLC (thin-layer chromatographic) technique to concentrate, rather than separate, the fluorescent compounds in oil in one area of the chromatogram. The limit of detection on the chromatogram is 2 micrograms of Empire Mix or Saudi Arabian crude oil. This method is not intended to identify sources of oil in sediments (finger-printing), nor to determine the total quantity of oil in sediments; rather, it is a rapid, inexpensive field method for locating areas where the sediments contain oil and for estimating the relative amount of oil in comparison to adjacent areas. The utility of the method has been demonstrated in trials conducted aboard ship during a sampling trip in the Gulf of Mexico and on sediment samples collected in response to the ARGO MERCHANT spill incident.

Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1977
Accession Number
ADA042976

Entities

People

  • Lewis Raymond Brown

Organizations

  • Mississippi State University

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Buildings And Structures
  • Detection
  • Materials Laboratories
  • Medical Personnel
  • Migration
  • Oil Spills
  • Petroleum
  • Printing
  • Research Facilities
  • Sampling
  • Sediments

Readers

  • Analytical Chemistry
  • Coastal and Marine Engineering/Sediment Transport/Hydraulic Engineering
  • Systems Analysis and Design