Oxidation of Phossy Water by Ozone.

Abstract

This work was undertaken to establish the feasibility of using ozone to lower the elemental phosphorus level of phosphorus contaminated water at Edgewood Arsenal. Separate samples of this phossy water were treated with ozone at various mass rates in a sparged stirred reactor. The ozone repeatedly reduced the elemental phosphorus concentration below the limits of detection. Simple aeration also oxidized the white phosphorus but not at the rate nor to the extent that ozone showed. No correlation could be developed between elemental phosphorus lowering and its extent of conversion to the phosphate form. A white precipitate comprised mainly of calcium phosphate formed as the phossy water was oxidized. Thus, preliminary data resulted which prove the feasibility of using ozone to treat phossy water and which will lead the way for further studies in this area.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1977
Accession Number
ADA044753

Entities

People

  • Donald L. Campbell

Organizations

  • United States Army Armament Research, Development and Engineering Center

Tags

Communities of Interest

  • Biomedical
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Aeration
  • Calcium
  • Calcium Compounds
  • Conversion
  • Detection
  • Elements
  • Flow Rate
  • Gas Flow
  • Generators
  • Munitions
  • Oxidation
  • Phosphorus
  • Research Facilities
  • Schematic Diagrams
  • Storage Tanks
  • Weapons
  • Weapons Support Equipment

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Environmental Engineering
  • Marksmanship and Weaponry.