Dioxetanone Chemiluminescence by the Chemically Initiated Electron Exchange Pathway. The Efficient Generation of Excited Singlet States.

Abstract

The chemiluminescence of dimethyldioxetanone (1) in the presence of easily oxidized aromatic hydrocarbons was studied. It was observed that the rate of reaction of (1) depends upon the nature and concentration of the aromatic hydrocarbon. The efficiency of light production was correlated with the one electron oxidation potential of the hydrocarbon. These results are interpreted in terms of the recently described chemically initiated electron exchange luminescence. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Oct 14, 1977
Accession Number
ADA045864

Entities

People

  • Gary Schuster
  • Steven P. Schmidt

Organizations

  • University of Illinois Urbana–Champaign

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aromatic Hydrocarbons
  • California
  • Chemical Reactions
  • Chemiluminescence
  • Chemistry
  • Civil Engineering
  • Cyclic Hydrocarbons
  • Demographic Cohorts
  • Electron Transfer
  • Hydrocarbons
  • Illinois
  • Luminescence
  • Materials Science
  • Military Research
  • New York
  • Oxidation
  • United States

Fields of Study

  • Chemistry

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Molecular Photonics/Laser Physics

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene