Utilization of Aluminum Alloy Anodes for an Electrochemical Heater.

Abstract

A magnesium/manganese dioxide cell has been developed for direct heating of field rations under short-circuit conditions. Although fast and convenient, the cell has the disadvantage of producing considerable hydrogen gas during its operation, thereby presenting a potential explosion hazard. This report deals with an electrochemical analysis of the hydrogen evolution problem in the magnesium/manganese dioxide heater cell and with the exploration of aluminum alloys as low-gassing substitutes for magnesium in such a cell. The results reveal that, in the early period of discharge of a magnesium cell, most of the hydrogen is produced at the anode. Gas production becomes more significant at the cathode during the latter period of cell discharge. The use of an aluminum alloy anode of a particular composition greatly reduces the problem of gassing at the anode and completely eliminated gassing at the cathode. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1977
Accession Number
ADA046116

Entities

People

  • P. Bramhall
  • S. Gilman

Organizations

  • United States Army Communications-Electronics Command

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aluminum Alloys
  • Cells
  • Chemistry
  • Current Density
  • Electrochemical Cells
  • Electrodes
  • Energy
  • Equations
  • Films
  • Gas Evolution
  • Heat Transfer
  • Materials
  • Measurement
  • Metals
  • Mixtures
  • Short Circuits
  • Standards

Fields of Study

  • Materials science

Readers

  • Battery Technology and Engineering
  • Materials Science and Engineering.
  • Systems Analysis and Design