The Preparation of (3-3-(Ph3P)2-3-H-4-(polystyrylmethyl)-3-1-2-Rhoda Carborane); A Polymer-Bound Metallocarborane Catalyst.

Abstract

The compound (3-3-(Ph3P)2-3-H-4-(polystyrylmethyl)-3-1-2-RhC2B9H10)(I) was synthesized from ((Ph3P)3RhC1) and (9-(polystyrylmethyl)-7-8-C2B9H11) M+ (II; M = Na or K). Characterization of (I) includes infrared, visible, and X-ray photoelectron spectroscopy and elemental analysis. The polymer-bound carborane (II) was isolated from the reaction of (7,8-C2B9H11)2- with Merrifield's Peptide resin.

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Document Details

Document Type
Technical Report
Publication Date
Oct 25, 1977
Accession Number
ADA046240

Entities

People

  • B. A. Sosinsky
  • M. Frederick Hawthorne
  • R. A. Grey
  • V. A. Uski
  • W. C. Kalb

Organizations

  • University of California, Los Angeles

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  • Counter IED

DTIC Thesaurus Topics

  • Alkenes
  • Analogs
  • Chemical Synthesis
  • Chemistry
  • Elements
  • Hydrogenation
  • Military Research
  • Navy
  • Photoelectrons
  • Polymers
  • Resins
  • Spectra
  • Spectroscopy
  • X Ray Photoelectron Spectroscopy
  • X Rays

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  • Chemistry

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  • Organic Chemistry
  • Spectroscopy.

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  • Microelectronics