Thermally Stable Polymers.

Abstract

Electrophilic trisubstituted ethylenes, where X, Y, Z are electro-negative substituents, CN, COOCH3, Cl, and F have been synthesized. They do not homopolymerize but readily undergo free radical copolymerization with electron-rich vinyl monomers such as styrene. The copolymers, obtained in reasonably high molecular weights, have glass transition temperatures in the 150-225 C. range, decomposed in the 225-275 range, and were soluble in many organic solvents. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Sep 15, 1977
Accession Number
ADA046347

Entities

People

  • Hary K. Hall Jr.
  • Maurizio Lenarda
  • Pierre A. Ykman
  • Walter Fischer

Organizations

  • University of Arizona

Tags

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Chemical Synthesis
  • Chemistry
  • Cyclic Hydrocarbons
  • Ethylenes
  • Glass Transition Temperature
  • Military Research
  • Molecular Weight
  • Organic Chemistry
  • Organic Solvents
  • Polymerization
  • Polymers
  • Transition Temperature

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology

Technology Areas

  • Microelectronics