The Effects of Velocity on Corrosion of Galvanic Couples in Seawater.

Abstract

The effects of velocity on the corrosion of galvanic couples (70/30 Cu-Ni/plain carbon steel and K-Monel/plain carbon steel) in synthetic seawater electrolyte were studied. A unique experimental apparatus was designed and built, employing a foil-shaped specimen holder rotating in a tank, and the hydrodynamic flow conditions within the test system were carefully characterized. Galvanic current measurements were taken at various velocities and corrosion product formation and dissolution patterns were studied. A model is developed which considers both hydrodynamic and electrochemical boundary layer effects, and the role of the polarization characteristics of the individual metals is discussed. The development of corrosion products, protective oxide films, and surface metal removal are discussed. A corrosion product growth/removal cycle and consequent surface metal removal sequence is hypothesized under dynamic conditions. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1977
Accession Number
ADA048669

Entities

People

  • Gary Alan Storm

Organizations

  • Naval Postgraduate School

Tags

Communities of Interest

  • Advanced Electronics
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Alloys
  • Boundary Layer
  • Carbon Steels
  • Chemical Synthesis
  • Chemistry
  • Corrosion
  • Corrosion Inhibition
  • Corrosion Resistance
  • Engineers
  • Fluid Dynamics
  • Fluid Flow
  • Galvanic Corrosion
  • Materials
  • Measurement
  • Mechanical Properties
  • Naval Architecture
  • Solid Solutions

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Marine Hydrodynamics
  • Materials Science and Engineering.