Inorganic Halogen Oxidizer Research.
Abstract
A simple method for the purification of fluorine is described. The formation of NF3(+) radical cation salts in the low-temperature uv-photolytic synthesis of NF4(+) salts was demonstrated by ESR spectroscopy. The mechanism of the NF4(+) salt formation is discussed. Metathetical NF4(+) salt processes based on NF4BiF6 were studied. A previous literature claim for the synthesis of N2F5(+) salts is refuted. The novel N2F3(+) salts N2F3SnF5 and N2F3SbF6 were prepared and the planar structure of the N2F3(+) cation was established. The reaction chemistry of electropositive chlorine compounds with fluorocarbons was reviewed. The vibrational spectra and force fields of BrF3O, FBRO2, ClF4O(-), BrF4O(-), and If4O(-) were determined. The novel oxonium salt, H3O(+) BiF6(-) was prepared and its properties were investigated. Three patents on the syntheses of ClF3O2, nitryl perchlorate, and anhydrous metal perchlorates were issued.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 25, 1978
- Accession Number
- ADA050133
Entities
People
- C. J. Schack
- K. O. Christe
- R. D. Wilson
- W. W. Wilson