Structures of Metallocarboranes. VIII. Crystal and Molecular Structure of the Eleven-Vertex Heterobimetallocarborane 1,8-Di-eta-cyclopentadienyl-1-ferra-8-cobalta-2,3-dicarbaundecaborane(9), 1,8-(eta-C5H5)2-1-Fe-8-C0-2,3-C2B7H9(1).
Abstract
Polyhedral metallocarboranes containing two different transition metal vertices can be prepared by use of either polyhedral expansion or polyhedral subrogation reactions on previously prepared metallocarboranes. To assess the effect of a one electron deficiency, the x-ray structural determination of (C5H5)2FeCoC2B7H9 was undertaken.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 18, 1978
- Accession Number
- ADA050326
Entities
People
- A. L. Sims
- C. B. Knobler
- F. Y. Lo
- K. P. Callahan
- M. Frederick Hawthorne
Organizations
- University of California, Los Angeles